Spanky, hope you are feeling better soon!
First off, at least at my store, they got a larger than usual supply of all the MSFs, blushes and shadows. If you can get down there Friday, I bet your store will still have stock.
I remember your coloring from photos you've posted. For the blushes, I'd say #1 will be Exotic Ember. Im NC15 and have freckles and it's the perfect shade to hide my freckles and still look like a sheer veil of sexy tanned color. It accentuates the bone structure wonderfully. If you prefer a less subtle type of blush, I'd say second best would be Simmer - it's versatile and unique.
For the MSFs I'd rank them for you as Adored > Rio > Lust, which is the same ranking I give them for myself, plus I think the Adored + Exotic Ember was an extra nice combo.
159 brush is awesome.
I've got green eyes and Bossa Blue was the sexiest, Tropica was lovely and unique, if possibly a little on the youthful side for me, and Time to Tango was great, but has glitter. Caribbean is a no-brainer color for green eyes, but you probably already have something similar. Same thing for Cha Cha Cha. Dare to Bare was a little run of the mill and also had glitter so definitely my least fave.
Hope this helps - don't worry too much - Temptalia will have pictures before Thurs. the way things are looking too, so there's that. (I wonder if she is going to LOVE or HATE the MSFs and blushes this time around. I feel like she may rush through her testing and decide she doesn't like them before she's found the best brush and technique to apply them, as she's done before with Mineralize.)